Removal of Pb(II) Ion from Aqueous Solution by an Engineered Novel Chitosan Functionalized Schiff-Base Adsorbent
Publish place: 26th Iranian Seminar on Organic Chemistry
Publish Year: 1397
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
ISOC26_185
تاریخ نمایه سازی: 2 شهریور 1398
Abstract:
A new adsorbent was synthesized to for the adsorption of Pb+2 from aqueous solutions.The magnetic chitosan-(d-glucosimine methyl) benzaldehyde, (MCS-Sch) was characterizedby Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM),energy dispersive X-ray spectroscopy (EDX), dynamic light scattering (DLS), vibrating samplemagnetometer (VSM) and X-ray Diffraction (XRD) [1]. Batch adsorption experimentswere done under various conditions, such as adsorbent dose, pH and contact time. The equilibriumdata were fitted to Langmuir and Freundlich isotherm models [2]. The maximummonolayer capacity obtained from the Langmuir isotherm was 121.10 mg/g. The MCS-Schwas found to be regenerated effectively up to five efficient cycles of adsorption/desorptionprocesses. The mechanism for Pb+2 adsorption onto MCS-Sch involved the interactions ofnitrogen and oxygen atoms and also aromatic rings with heavy metal followed by their adsorptionon the MCS-Sch.
Authors
Esmat Rahmanifar
Department of Chemistry, Faculty of Science, University of Zabol, Zabol, Iran
Somayeh Shahraki
Department of Chemistry, Faculty of Science, University of Zabol, Zabol, Iran
Fereshteh Shiri
Department of Chemistry, Faculty of Science, University of Zabol, Zabol, Iran