Copolymer coated magnetic graphene oxide; a reusable catalyst for the preparation of triaryl pyridines in solvent-free condition
Publish place: 27th Iranian Seminar on Organic Chemistry
Publish Year: 1398
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
ISOC27_211
تاریخ نمایه سازی: 19 اسفند 1399
Abstract:
The pyridine rings have been found in the structure of many natural products such as nicotinic acid, vitamin B6, and NAD nucleotides.1 In recent years, various methods have been used for the synthesis of pyridine derivatives. But one of the best methods for the preparation of pyridine derivatives is the use of multicomponent reactions. In recent years, the synthesis of pyridine compounds has been carried out using various catalysts such as H14[NaP5W30O110],2 Bi(OTf)3,3 MgAl2O4,4 ZrOCl2,5 CoCl2 6H2O.6Although some of these methods are valuable, most of them have several disadvantages such as long reaction times, requiring large amounts of catalyst and the use of toxic or non-reusable reagent. Therefore, development of a facile and economical synthetic route to 2,4,6-triarylpyridines is still in demand. Herein, we apply a copolymer coated magnetic graphene oxide for the first time as a green and reusable nanocatalyst in the synthesis of these biologically active heterocycles from benzaldehydes, acetophenones and ammonium acetate in solvent-free conditions
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Authors
Seyedeh Fatemeh Hojati
Department of Chemistry, Hakim Sabzevari University, Sabzevar, Iran
Amirhassan Amiri,
Department of Chemistry, Hakim Sabzevari University, Sabzevar, Iran
Sara Ghavidel
Department of Chemistry, Hakim Sabzevari University, Sabzevar, Iran