Coordination of a norbornene ligand toward the Zinc(II) ion: spectral, structural and docking studies
Publish Year: 1401
نوع سند: مقاله کنفرانسی
زبان: English
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شناسه ملی سند علمی:
NANOTEC06_009
تاریخ نمایه سازی: 21 خرداد 1402
Abstract:
In this project, we prepared a new complex of zinc, [Zn(PACN)(Br۲)], with ۲,۹-di(piperidin-۲-yl)-۱,۳,۶-triazabicyclo[۴.۲.۱]nonane (PACN) and identified by elemental analysis, FT-IR spectroscopy and single X-Ray diffraction. In the crystal structure of this complex, zinc atom has a ZnN۳Br۲ environment with square-pyramidal geometry and the coordination number of zinc(II) ion in this complex is ۵. The L portion is potentially five-dentate ligand wich can bind metal atom through five N-atoms. In this compound the ligand acted as tridentate and forms two five membered chelate rings. In the crystal network of the complex there is intermolecular C–H···Br hydrogen bonds, extending the crystal network into three dimensional
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Authors
Zahra Mardani
Inorganic Chemistry Department, Faculty of ChemistryUrmia University, ۵۷۵۶۱-۵۱۸۱۸Urmia,Iran
Safoura Sefidkar
Inorganic Chemistry Department, Faculty of ChemistryUrmia University, ۵۷۵۶۱-۵۱۸۱۸Urmia,Iran